SYNTHESIS, CHARACTERIZATION AND CATECHOLASE ACTIVITY OF COBALT (II) COMPLEXES WITH PHENOL BASED N2O2 CHELATING LIGAND
نویسندگان
چکیده
منابع مشابه
synthesis and characterization of some new cyclometalated organoplatinum(ii) complexes containing phosphite ligand
در این تحقیق روشی جهت سنتز یک سری از کمپلکس های پلاتین (ii) حاوی لیگاند های دهنده ی فسفری شامل فسفیت و فسفین ارائه شده است. واکنش پیش ماده ی پلاتین (ii)،trans/cis- [ptcl2(sme2)2] ، با 2 اکی مولار از لیگاند p(oph)3در حلال بنزن کمپلکس1، cis-[ptcl2(p(oph)3)2] را تولید می نماید. جهت سنتز کمپلکس سایکلو متال فسفیتی، کمپلکس 1 با 1 اکی والان واکنشگر ptcl2 در حلال زایلن در شرایط رفلاکس زیر گاز آرگون م...
Synthesis and Characterization of New Mercury (II) Complexes with Bidentate Chelating Schiff Base Iminopyridine Ligand
First, Schiff base iminopyridine ligands has been prepared by the condensation between primaryamines, different substituted anilines and active carbonyl group of pyridine carboxaldehyde, thenthe complexes [diiodo (3-ethylphenyl) pyridine-2-yl methylene amine] mercury(II), complex a,[dibromo (2,5-dimethylphenyl) pyridine-2-yl methylene amine] mercury(II) complex b, and[dinitrato bis-(2,6-dimethy...
متن کاملThe synthesis, characterization and catecholase activity of dinuclear cobalt(ii/iii) complexes of an O-donor rich Schiff base ligand
Three dinuclear Co complexes [(Co2(H2L)2(OAc)2)] CH3OH (1), [CoCo(H2L)2(OAc)] 2CH3OH H2O (2), and [CoCo(H2L)2(CH3CN)(H2O)]Cl CH3CN 4H2O (3) [H4L is (3,5-di-tert-butyl-2-hydroxybenzylideneamino)-2(hydroxymethyl)propane-1,3-diol] were synthesized and characterized using single crystal X-ray diffraction and other analytical methods. Complex 1 having two Co centres was the only one found to show ca...
متن کاملSynthesis, characterization, antibacterial activity and molecular modeling studies of Ni(II) and Zn(II) complexes with phenylpyridylformamidine ligand
The Ni(II) and Zn(II) complexes with phenylpyridylformamidine (PhPyF) ligand, [Ni(PhPyF)Cl2] and [Zn(PhPyF)Cl2], have been prepared and investigated using different chemical techniques such as elemental analysis, molar conductance, FT-IR, UV-vis spectra and magnetic moment. The obtained chemical analysis data showed the formation of 1:1 (metal: ligand) ratio. The square planar and tetrahedral g...
متن کاملsynthesis and characterization of potentially biological active cyclometallated organoplatinum(ii) complexes
this work is presented in five parts. in the first part preparation of the starting complex [pt(c^n)cl(dmso)], 1, in which c^n = n(1),c(2?)-chelated, deprotonated 2-phenylpyridine, and dmso = dimethylsulfoxide, and its reaction with 1 equiv of the biphosphine ligands bis(diphenylphosphino)amine, dppa, or bis(diphenylphosphino)methane, dppm, to give the complex [pt(c^n)cl(dppa)], 2, or [pt(c^n)c...
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ژورنال
عنوان ژورنال: Rasayan Journal of Chemistry
سال: 2019
ISSN: 0974-1496,0976-0083
DOI: 10.31788/rjc.2019.1225230